[2,3]Sigmatropic Rearrangements ofN-Benzyl-N-methyl-N(2-alkenyl)ammoniumN-Methylides
- 1 January 1988
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1988 (12) , 988-990
- https://doi.org/10.1055/s-1988-27778
Abstract
Fluoride-ion induced desilylation of N-benzyl-N-methyl-N-(2-alkenyl)-N-[(trimethylsilyl)methyl]ammonium halides gave N-methylide intermediates which were isomerized to N-methyl-N-(2-alkenyl)-2-methylbenzylamines (Sommelet-Hauser rearrangement products) and N-methyl-N-(3-alkenyl)benzylamines (allyl rearrangement products) in DMF at room temperature.Keywords
This publication has 0 references indexed in Scilit: