RADIATION CHEMISTRY OF CYCLOHEXANE: I. ISOTOPIC COMPOSITION OF HYDROGEN EVOLVED FROM MIXTURES OF C6D12 AND C6H12
- 1 April 1960
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 38 (4) , 539-543
- https://doi.org/10.1139/v60-076
Abstract
The yield of D2 formed by a unimolecular process in the γ-ray irradiation of cyclohexane-d12 has been deduced from the isotopic composition of hydrogen evolved from C6H12–C6D12 mixtures. A value of 0.25 molecule/100 ev is found for this "molecular" yield. This yield is only slightly reduced by iodine but is considerably reduced in the presence of biphenyl.Keywords
This publication has 3 references indexed in Scilit:
- Radiation Chemistry of Organic Compounds. IV. CyclohexaneThe Journal of Physical Chemistry, 1959
- Radiolysis of Ethane: Isotopic and Scavenger StudiesThe Journal of Physical Chemistry, 1958
- Radiation Chemistry of Organic Compounds. II. n-HexaneThe Journal of Physical Chemistry, 1958