A novel stereospecific synthesis of 5-amino-1-β-D-fructofuranosylimidazole-4-carboxamide
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 671-672
- https://doi.org/10.1039/c39880000671
Abstract
A β-D-fructofuranose fused oxazolidine-2-thione has been isolated as the t-butyldimethylsilyl derivative (6), which when desulphurised and treated with α-amino-α-cyanoacetamide gave the silylated 1-β-D-fructofuranosyl aminoimidazole (2b) which when deblocked with methanolic hydrogen chloride produced 5-amino-β-D-fructofuranosyl-imidazole-4-carboxamide (2a).Keywords
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