A new reaction vessel for accelerated syntheses using microwave dielectric super-heating effects
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 7,p. 1151-1155
- https://doi.org/10.1039/dt9920001151
Abstract
Using a thick-walled glass reaction vessel a number of transition-metal organometallic and co-ordination compounds have been synthesised using microwave dielectric super-heating effects. Super-heating by 40–60 °C is maintained by controlling the pressure at 10 atm and results in a decrease in the reaction time required for conventional reflux reactions by a factor of ca. 102. Full details of the design of the apparatus, the modification of a conventional microwave oven and the electrical circuitry for the pressure control are provided.Keywords
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