Allylic stereocenter directed asymmetric conjugate addition of cuprates in the presence of trimethylchlorosilane. enantioselective synthesis of 2-alkyl-4-benzyioxybutanal and 2-alkyl-4-oxopentanal
- 1 January 1988
- journal article
- Published by Elsevier in Tetrahedron
- Vol. 44 (18) , 5929-5938
- https://doi.org/10.1016/s0040-4020(01)81451-4
Abstract
No abstract availableKeywords
This publication has 19 references indexed in Scilit:
- Norephedrine-derived 2-alkenyloxazolidines: stereochemistry of cyclization and allylic stereocenter directed asymmetric conjugate additionThe Journal of Organic Chemistry, 1988
- A highly stereoselective total synthesis of the natural enantiomer of olivinJournal of the American Chemical Society, 1987
- Organocopper conjugate addition reaction in the presence of trimethylchlorosilaneTetrahedron Letters, 1986
- Fumaraldehyde monodimethyl acetal: An easily accessible and versatile intermediate.Tetrahedron Letters, 1986
- Allylic stereocenter directed asymmetric conjugate addition. Enantioselective synthesis of 3-alkylsuccinaldehydic acid methyl estersThe Journal of Organic Chemistry, 1986
- Me3SiCl accelerated conjugate addition of stoichiometric organocopper reagentsTetrahedron Letters, 1986
- Me3SiCl/HMPA accelerated conjugate addition of catalytic copper reagent. Stereoselective synthesis of enol silyl ether of aldehydeTetrahedron Letters, 1986
- Evidence for a reversible d, π-complexation, β-cupration sequence in the conjugate addition reaction of Gilman reagents with α,β-enones.Tetrahedron Letters, 1985
- The reactions of combined organocuprate-chlorotrimethylsilane reagents with conjugated carbonyl compoundsTetrahedron Letters, 1985
- d-orbital stereoelectronic control of the stereochemistry of SN2′ displacements by organocuprate reagentsTetrahedron Letters, 1984