Hydroboration/Amination of N-Trimethylsilyl Protected Olefinic Amines and Diolefins: Synthesis of Isomerically Pure Diamines
- 1 July 1990
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 20 (14) , 2113-2118
- https://doi.org/10.1080/00397919008053146
Abstract
N-Trimethylsilyl protected olefinic amines and terminal diolefins were hydroborated with dimethylborane and the resulting organoboranes were treated with in situ generated chloramine or chloroalkylamines to produce isomerically pure diamines or N-substituted diamines in good yields.Keywords
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