Chiral allenes are racemised by organocuprates
- 1 January 1979
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 524-525
- https://doi.org/10.1039/c39790000524
Abstract
The chiral allenes (1) and (2) are racemised in the presence of various organocuprates, or, in the case of the alcohol (2), by methylmagnesium iodide alone; the racemisations probably proceed via an anion radical.Keywords
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