Influence of vibrational excitation energy on the cyclisation stereochemistry of triplet 1,3-biradicals
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 615b-616
- https://doi.org/10.1039/c3972000615b
Abstract
1,4-Hydrogen migration in triplet 3-methylbut-1-ene produces the triplet 1,2-dimethyl-1,3-trimethylene biradical which can subsequently cyclise to trans- and cis,2-dimethylcyclopropane in a ratio strongly dependent on its internal vibrational energy.Keywords
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