Application of 18O induced isotope effects in 13C n.m.r. spectroscopy to the biosynthesis of asteltoxin

1 January 1985

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 22,p. 1633-1635
https://doi.org/10.1039/c39850001633

Abstract

Observation of ¹⁸O induced isotope shifts in the ¹³C n.m.r. spectra of asteltoxin derived from [1-¹³C, ¹⁸O₂]acetate and ¹⁸O₂ gas established the origin of the oxygen atoms and clarified the mechanism of the formation of the 2,8-dioxabicyclo[3.3.0]octane moiety.

Keywords

ISOTOPE EFFECT

This publication has 0 references indexed in Scilit: