Synthesis and characterization of oxomolybdate clusters containing co-ordinatively bound diazenido units. The crystal and molecular structure of the octanuclear oxomolybdate (NHEt3)2(NBu4)2[Mo8O20(NNPh)6]
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1749-1750
- https://doi.org/10.1039/c39850001749
Abstract
Treatment of α-(NR4)4[Mo8O26] with an excess of phenylhdrazine in ethanol and fractional crystallization yielded a tetranuclear species, [Mo4O8(OEt)2(NNph)4]2–, with bridging ethoxy groups, and an octanuclear complex, [Mo8O20(NNPh)6]4–, structurally related to the α-[Mo8O26]4– precursor, as determined by X-ray crystallography; the structure of the Mo8 precursor is reported.Keywords
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