Homogeneous catalysis. Production of allyl alkyl sulphides by palladium mediated allylation
- 1 January 1986
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 146-147
- https://doi.org/10.1039/c39860000146
Abstract
The use of O-allyl S-alkyl dithiocarbonate substrates in palladium mediated catalytic allylation gives carbonyl sulphide and allyl alkyl sulphides with net retention of configuration and their use obviates the problems associated with sulphur nucleophiles in catalytic allylation.Keywords
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