An Unusual N-Dealkylation-Neighbouring Group Participations of Oximino Function [1]
Open Access
- 1 October 1979
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 34 (10) , 1424-1426
- https://doi.org/10.1515/znb-1979-1015
Abstract
Reaction of N,N-dialkyl-β-aminoketones (5 and 7) with hydroxylamine hydrochloride in pyridine results in the dealkylated oximine (6). The mechanism of this N-dealkylation may be explained as due to the neighbouring group participation of the oximine formed during the reaction.Keywords
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