Oxidation of iron in titania-supported iron–ruthenium under reducing conditions: in situ evidence from57Fe Mössbauer spectroscopy

Abstract
In situ studies of ruthenium-rich iron-ruthenium clusters supported on titania of differing surface areas by 57Fe Mössbauer spectroscopy show that the pre-reduced bimetallic phase undergoes partial oxidation when treated in atmospheres of hydrogen or hydrogen and carbon monoxide.
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