Evidence from activation volumes for an eliminative mechanism in the hydrolysis of 2,4-dinitrophenyl 4-hydroxybenzoate

1 January 1984

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 20,p. 1361-1362
https://doi.org/10.1039/c39840001361

Abstract

A positive volume of activation is found for the hydrolysis of 2,4-dinitrophenyl 4-hydroxybenzoate, differentiating its mechanism from the B_AC2 route used by other esters, all of which have negative values.

Keywords

ELIMINATIVE MECHANISM
DIFFERENTIATING
BAC2 ROUTE
NEGATIVE VALUES
POSITIVE VOLUME
ROUTE USED
ESTERS
VOLUME OF ACTIVATION
EVIDENCE

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