Surface Specific Heat of an Isotropic Solid at Low Temperatures
- 1 November 1960
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 33 (5) , 1452-1461
- https://doi.org/10.1063/1.1731426
Abstract
The effect of realistic boundary conditions on the computation of the specific heat of an isotropic solid at low temperatures is investigated. Two cases are considered: the surface free of stress and the surface rigidly clamped. The first of these is the one of physical interest. For both cases a term in the specific heat arises which is proportional to the surface area and to T2 and appreciably higher than Montroll's result in the case of the free solid. The effect of approximations introduced during the computation is estimated. Available experimental data are not adequate for a critical test of the theory.Keywords
This publication has 20 references indexed in Scilit:
- On the heat capacity of crystalline magnesium oxideProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1959
- Heat Capacity of Small Particles of MgO between 1.5° and 4°KThe Journal of Chemical Physics, 1958
- A LOW TEMPERATURE PARTICLE SIZE EFFECT ON THE HEAT CAPACITY OF SODIUM CHLORIDECanadian Journal of Chemistry, 1955
- The Specific Heat of Small Particles at Low TemperaturesJournal of the American Chemical Society, 1952
- The Adiabatic Elastic Constants of Rock SaltPhysical Review B, 1951
- Lattice dynamics and X-ray scatteringProceedings of the Physical Society, 1942
- Distribution of Eigentones in a Rectangular Chamber at Low Frequency RangeThe Journal of the Acoustical Society of America, 1939
- Frequency Distribution of Eigentones in a Three-Dimensional ContinuumThe Journal of the Acoustical Society of America, 1939
- THE MEASUREMENT OF COEFFICIENTS OF EXPANSION AT LOW TEMPERATURES: SOME THERMODYNAMIC APPLICATIONS OF EXPANSION DATAJournal of the American Chemical Society, 1926
- ber die Eigenwerte bei den Differentialgleichungen der mathematischen PhysikMathematische Zeitschrift, 1920