Hydration effect on titanium linkage to silicalite framework
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 685-687
- https://doi.org/10.1039/c39930000685
Abstract
An EXAFS multishell analysis of a titanium silicalite with an MFI structure reveals that the double Si–O–Ti bridges formed between [TiOx] species and the [SiO4] framework tetrahedra are partially hydrolysed in the presence of water which results in the conversion from an edge- to a corner-sharing type of bonding between the two structural units.Keywords
This publication has 0 references indexed in Scilit: