Preparation, aquation, and hydrogen exchange of the chloropentakis(methylamine)cobalt(III) ion
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 583-586
- https://doi.org/10.1039/j19670000583
Abstract
The preparations and hydrogen exchange of the complex ions Co(MeNH2)5Cl2+ and Co(MeNH2)5OH2 3+ are described. The rate of acidic hydrolysis of the former into the latter has been determined. Evidence is presented suggesting that the chloro ligand has a strong labilising influence upon the trans-amine's hydrogen whereas the aquo ligand does not, and that the cis-amine's hydrogen is relatively little affected in either case.Keywords
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