Preparation and properties of 1-adamantylmethyl and adamantyl complexes of transition metals
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 10,p. 1879-1887
- https://doi.org/10.1039/dt9800001879
Abstract
The syntheses and characteristic properties of a variety of 1-adamantylmethyl (R = 1-adme) compounds of transition metals are described. These include peralkyls, MRn(M = Ti, V, Cr, Mn, or Zr); mixed complexes, MRnXm(X = OBut or Cl, M = V, Nb, or Ta); π-acid complexes, MR2L2(L = P- or N-donor) including the first example of a thermodynamically favoured trans-dialkylplatinum(II) derivative. Additionally, the preparations of bis(1- adamantyl)- and bis(2-adamantyl)-magnesium are reported, as well as successful and inconclusive attempts to produce Cr(ad)4(ad = 1- or 2-adamantyl).Keywords
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