α‐Deprotonierung eines α‐chiralen 2‐Alkenylcarbamats unter Retention und Lithium‐Titan‐Austausch unter Inversion ‐ zur Homoaldol‐Reaktion unter 1,3‐Chiralitätsübertragung
- 1 February 1986
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 98 (2) , 171-173
- https://doi.org/10.1002/ange.19860980212
Abstract
No abstract availableKeywords
This publication has 25 references indexed in Scilit:
- Metallierte Stickstoff‐Derivate der Kohlensäure in der organischen Synthese, XXVII. – Homoaldol‐Reaktion, VII. Lithiierung acyclischerN,N‐Dialkylcarbamidsäure‐2‐alkenylester; Silylierung und γ‐selektive α‐Hydroxyalkylierung von Homoenolat‐ReagenzienEuropean Journal of Inorganic Chemistry, 1985
- The Homoaldol Reaction, or How to Overcome Problems of Regio‐ and Stereo‐selectivityAngewandte Chemie International Edition in English, 1984
- Die Homoaldol-Reaktion oder wie man Probleme der Regio- und Stereoselektivität in den Griff bekommtAngewandte Chemie, 1984
- Alkoxy stabilization and synthetic utility of tetrahedral carbanionsJournal of the American Chemical Society, 1984
- Two-flask preparation of .alpha.-lithio cyclic ethers from .gamma.- and .delta.-lactones. Reductive lithiation as a route, via radical intermediates, to axial 2-lithiotetrahydropyrans and their equilibration to the equatorial isomersJournal of the American Chemical Society, 1984
- Organotitanium reagents in organic synthesis a simple means to adjust reactivity and selectivity of carbanionsPublished by Springer Nature ,1982
- Kinetic resolution of racemic allylic alcohols by enantioselective epoxidation. A route to substances of absolute enantiomeric purity?Journal of the American Chemical Society, 1981
- .alpha.-Alkoxyorganolithium reagents. A new class of configurationally stable carbanions for organic synthesisJournal of the American Chemical Society, 1980
- Synthetic studies on (2R,4'R,8'R)-.alpha.-tocopherol. Facile syntheses of optically active, saturated, acyclic isoprenoids via stereospecific [3,3] sigmatropic rearrangementsThe Journal of Organic Chemistry, 1976
- .alpha.-Methoxy-.alpha.-trifluoromethylphenylacetic acid, a versatile reagent for the determination of enantiomeric composition of alcohols and aminesThe Journal of Organic Chemistry, 1969