A self-assembling polymer-bound rotaxane under thermodynamic control
- 16 May 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 12,p. 1396-1397
- https://doi.org/10.1039/b302071a
Abstract
The thermodynamically controlled self-assembly of a neutral donor–acceptor rotaxane, stoppered via porphyrin coordination and bound to polystyrene beads is described, and the dynamic equilibrium between solid and solution phases has been examined by HR MAS nmr spectroscopy.Keywords
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