Stereoselective Cyclopolymerization of 1,5-Hexadiene Using Novel Bis(ferrocenyl)zirconocene Catalyst
- 1 October 1995
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 24 (10) , 905-906
- https://doi.org/10.1246/cl.1995.905
Abstract
A novel heterotrinuclear zirconium-iron complex 1 was synthesized and crystal structure of 1 was determined by X-ray diffraction method. The complex 1 efficiently catalyzed cyclopolymerization of 1,5-hexadiene in the coexistence of methylaluminoxane to afford trans-poly(methylene-1,3-cyclopentane) with high stereoselectivity (98% trans).Keywords
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