Fluorescence of nitric oxide excited by the 184.9 nm mercury resonance line
- 15 December 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 63 (12) , 5470-5474
- https://doi.org/10.1063/1.431282
Abstract
The fluorescence of NO was obtained by excitation from the 184.9 nm resonance line of a low pressure mercury lamp. It was found that the β (v′=9) emission was induced by the absorption of the 184.9 nm line for [NO]=1.0 torr. Quenching of the β (v′=9) bands by He or N2 molecules was accompanied by an enhancement of the γ bands, v′=4 or 0 and 1, respectively. When CO was added to NO, intensities of the emission were weakened. These effects were explained by the following reaction scheme.Keywords
This publication has 35 references indexed in Scilit:
- Predissociation and its inverse, using resonance absorption NO(C 2Π) ⇄ N+OThe Journal of Chemical Physics, 1973
- CO(a 3Π), Its Production, Detection, Deactivation, and Radiative LifetimeThe Journal of Chemical Physics, 1971
- Comparison of the reactivities of the lowest excited states of nitrogen (A3.SIGMA.u+) and of carbon monoxide (a3.PI.)Journal of the American Chemical Society, 1971
- Fluorescence of Nitric Oxide Excited by the 2139-Å Zinc Resonance LineThe Journal of Chemical Physics, 1971
- Rates of energy transfer from N2 A 3? + u to various molecules. Initial and final quantum states in the transfer to NOX 2? and Hg(61 S 0), and vibrational relaxation of N2 A 3? + u (v= 1) in heliumTransactions of the Faraday Society, 1971
- Reactions of N2(A3Σ+u)Published by American Chemical Society (ACS) ,1969
- Potential energy curves for N2, NO, O2 and corresponding ionsJournal of Quantitative Spectroscopy and Radiative Transfer, 1965
- Fluorescence of nitric oxide. Part 3.—Determination of the rate constants for predissociation, collisional quenching, and Spontaneous radiation of NO C2Π(v= 0)Discussions of the Faraday Society, 1964
- Fluorescence of nitric oxide. Part 2.—Vibrational energy transfer between NO A2Σ+(ν= 3, 2 and 1) and N2X1Σ+g(ν= 0)Transactions of the Faraday Society, 1963
- Fluorescence and vibrational relaxation of nitric oxide studied by kinetic spectroscopyProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1961