A CONVENIENT METHOD FOR THE PREPARATION OF VINYL SULFIDES AND OLEFINS BY THE USE OF TiCl4 AND Zn
- 5 January 1974
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 3 (1) , 37-38
- https://doi.org/10.1246/cl.1974.37
Abstract
β-Hydroxythioacetals or β-hydroxysulfides, prepared by the reactions of α-lithio thioacetals or α-lithio sulfides with aldehydes or ketones, were converted into vinyl sulfides or olefins in good yields by the treatment with TiCl4 and Zn.Keywords
This publication has 2 references indexed in Scilit:
- New synthetic method for ketone methylenation. Reductive elimination of phenylthiomethylcarbinyl estersJournal of the American Chemical Society, 1972
- A Useful Method for Reductive Fission of Sulfides and Its Application to Carbon-Carbon Bond FormationBulletin of the Chemical Society of Japan, 1971