Poly(2-oxazoline) block copolymers containing supramolecular segments
- 1 January 2000
- journal article
- Published by Taylor & Francis in Designed Monomers and Polymers
- Vol. 3 (3) , 245-253
- https://doi.org/10.1163/156855500750205538
Abstract
Metallo-supramolecular initiators based on 6-mono and 6,6′-bis-functionalized 2,2′-bipyridine metal complexes were utilized for the polymerization of different 2-oxazoline monomers. Polymers with a narrow molecular weight distribution and a predetermined molecular weight were obtained. The homo and block copolymers were characterized by GPC. Shear forces (e.g. on the GPC column) had a distinct influence on the star-like architecture, resulting in partially destruction.Keywords
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