Nickel(II)–bismuth(III) bond formation in nickel(II) complexes of tris(o-dimethylarsinophenyl)bismuthine
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 164-165
- https://doi.org/10.1039/c39750000164
Abstract
Tris(o-dimethylarsinophenyl)bismuthine (bitas) forms the square pyramidal complexes [Ni(bitas)X]BPh4(X = halide), the first examples of trivalent bismuth co-ordinated to a 3d transition metal in a positive oxidation state, and [Ni2(bitas)3]4+, which contains examples of bitas functioning as a tridentate and a tetra-dentate ligand.Keywords
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