Diels–Alder reactions of polyfluorocyclohexa-1,3-dienes. Part VI. Reactions of dodecafluorotricyclo[5,2,2,0]undeca-2,5,8-triene with ethylene and alkynes. A synthesis of polyfluorotricyclo[6,2,2,0]dodeca-2,4,6,9-tetraenes and 2,3-disubstituted hexafluoronaphthalenes
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1830-1835
- https://doi.org/10.1039/p19720001830
Abstract
Dodecafluorotricyclo[5,2,2,0]undeca-2,5,8-triene (1) reacts as a diene in Diels–Alder reactions. Pyrolysis of adducts from the triene (1) and alkynes can be controlled to give polyfluorotricyclo[6,2,2,0]dodeca-2,4,6,9-tetraenes or 2,3-disubstituted naphthalenes.Keywords
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