On the impedance of galvanic cells: II. Experimental verification
- 1 January 1960
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 79 (10) , 1101-1110
- https://doi.org/10.1002/recl.19600791014
Abstract
It is shown by experiment that both types of frequency dependency of the cell impedance, treated in Part I, occur. From the results the diffusion constant of the Hg++2 ion in 1M HClO4 and the reaction rate constant of the zinc amalgam electrode in 1M NaClO4 + 10−3M HClO4 base electrolyte are calculated. In addition the value of the double layer capacity of the zinc amalgam electrode is reported.Keywords
This publication has 2 references indexed in Scilit:
- über die kinetische Analyse des Entladungsmechanismus von Komplex-IonenZeitschrift für Physikalische Chemie, 1953
- Kinetics of rapid electrode reactions. Part 4.—Metal ion exchange reaction at amalgam electrodesTransactions of the Faraday Society, 1952