Silver complexes of 1,1′,3,3′-tetrakis(pyrazol-1-yl)propane: the “quadruple pyrazolyl embrace” as a supramolecular synthonElectronic supplementary information (ESI) available: two possible representations of the coordination sphere about Ag(2a) in 2·CH3CN. See http://www.rsc.org/suppdata/dt/b3/b301635h/
- 2 April 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- No. 9,p. 1712-1718
- https://doi.org/10.1039/b301635h
Abstract
The reaction between pyrazole and malonaldehyde bis(dimethylacetal) yields the first linked bis(pyrazolyl)methane ligand, CH2[CH(pz)2]2. Reaction of this ligand with Ag(O3SCF3) yields [Ag2{μ-CH2[CH(pz)2]}2](SO3CF3)2 (1). In the solid state 1 contains a dimeric dication in which two ligands sandwich two silver cations forming a bicyclic sixteen-membered ring system. A similar reaction with Ag(NO3) yields a trimetallic complex [Ag3{μ-CH2[CH(pz)2]2}2](NO3)3(CH3CN)2 (2) that crystallizes from acetonitrile as 2·CH3CN. Both 1 and 2 form supramolecular structures dominated by cooperative π–π stacking/CH–π hydrogen bonding interactions that we term the ‘quadruple pyrazolyl embrace.’ A Cambridge Structural Database search showed that this interaction is relatively common for metal complexes of simple poly(pyrazolyl)-methane or -borate ligands and occurs in a quarter of all cases.Keywords
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