Synthesis of (R)‐ and (S)2‐tert‐Butyl‐6‐trifluoro‐methyl‐1,3‐dioxin‐4‐ones, Transformations into 3‐Hydroxy‐3‐(trifluoromethyl)alkanoates, and Surprising Differences in the Reactivity of CH3‐ and CF3‐Substituted Compounds
- 1 August 1992
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 31 (8) , 1083-1085
- https://doi.org/10.1002/anie.199210831
Abstract
No abstract availableThis publication has 18 references indexed in Scilit:
- Structure and Reactivity of Five‐ and Six‐Ring N, N‐, N, O‐, and O, O‐acetals: A lesson in allylic 1, 3‐strain (A1, 3strain)Helvetica Chimica Acta, 1992
- Preparative Resolution of Heterocyclic Acetals Derived from Glycine, Mercapto‐acetic Acid, β‐Alanine, and Formyl‐ or Acetylacetic Acid by Recycling Chromatography onChiraspherand Temperature Dependence of Separation FactorsHelvetica Chimica Acta, 1991
- Aldol‐ und Michael‐Additionen fluorierter Nitroalkane an Aldehyde, Ketone und α,β‐ungesättigte Carbonylverbindungen1,2)European Journal of Inorganic Chemistry, 1991
- Stereoselective Construction of Molecules with a Trifluoromethyl Group.Journal of Synthetic Organic Chemistry, Japan, 1991
- (2R)‐5‐Alkyl‐2‐tert‐butyl‐6‐methyl‐4H ‐1,3‐dioxin‐4‐one als Zwischenprodukte zur Herstellung von α,β,β‐trisubstituierten β‐Hydroxycarbonsäuren unter Selbstregeneration des stereogenen Zentrums von (R)‐3‐HydroxybuttersäureEuropean Journal of Inorganic Chemistry, 1990
- Structure and Reactivity of Lithium Enolates. From Pinacolone to Selective C‐Alkylations of Peptides. Difficulties and Opportunities Afforded by Complex StructuresAngewandte Chemie International Edition in English, 1988
- α‐Alkylierung von β‐Hydroxycarbonsäuren über 1,3‐Dioxan‐4‐on‐EnolateHelvetica Chimica Acta, 1988
- Totally stereoselective additions to 2,6-disubstituted 1,3-dioxin-4-ones (chiral acetoacetic acid derivatives). Synthetic and mechanistic aspects of remote stereoselectivityJournal of the American Chemical Society, 1988
- Addition of Chiral Glycine, Methionine, and Vinylglycine Enolate Derivatives to Aldehydes and Ketones in the Preparation of Enantiomerically Pure α‐Amino‐β‐Hydroxy AcidsHelvetica Chimica Acta, 1987
- Diastereo- and Enantioselective Synthesis of Fluorinated ThreoninesSynthesis, 1985