Mechanism of Cyclic Carbonate Synthesis from Epoxides and CO2
Top Cited Papers
Open Access
- 30 March 2009
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 48 (16) , 2946-2948
- https://doi.org/10.1002/anie.200805451
Abstract
Three interconnected catalytic cycles account for the title reaction catalyzed by a bimetallic aluminum(salen) complex and Bu4NBr. In the first, Bu4NBr acts as a nucleophile to activate the epoxide. In the second, Bu3N generated in situ serves to activate CO2. In the third, the aluminum(salen) complex brings the two activated species together so that the key bonds can be formed intramolecularly.Keywords
This publication has 48 references indexed in Scilit:
- Utilisation of CO2 as a chemical feedstock: opportunities and challengesDalton Transactions, 2007
- Transformation of Carbon DioxideChemical Reviews, 2007
- Aspects of carbon dioxide utilizationCatalysis Today, 2006
- Chemical fixation of CO2 in carbonates: Routes to valuable products and long-term storagePublished by Elsevier ,2006
- The contribution of the utilization option to reducing the CO2 atmospheric loading: research needed to overcome existing barriers for a full exploitation of the potential of the CO2 useCatalysis Today, 2004
- Utilization of carbon dioxide in heterogeneous catalytic synthesisApplied Organometallic Chemistry, 2000
- Catalysts for the reactions of epoxides and carbon dioxideCoordination Chemistry Reviews, 1996
- Organic CarbonatesChemical Reviews, 1996
- LIII.—The action of heat on the chlorides and hydroxides of mixed quaternary ammonium compoundsJournal of the Chemical Society, Transactions, 1890
- IX. Contributions towards the history of the monamines.—No. III. Compound ammonias by inverse substitutionProceedings of the Royal Society of London, 1860