The reactivity dependence of the recombination probability
- 1 April 1980
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 72 (7) , 3904-3908
- https://doi.org/10.1063/1.439672
Abstract
An exact relation for the reactivity dependence of the recombination probability in the presence of a scavenger is derived. For a spherical symmetric system with a uniformly distributed scavenger this relation expresses the partially diffusion controlled recombination probability in terms of the totally diffusion controlled recombination probability. The relation is valid for a space‐dependent diffusion coefficient and for an arbitrary potential energy between the particles. The relation is proved only for a three‐dimensional system, but it appears to be valid also for one‐ and two‐dimensional systems.Keywords
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