Baeyer–Villiger oxidation of norbornan-7-ones: long-range substituent effects on regioselectivity
- 1 January 1998
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 3,p. 505-508
- https://doi.org/10.1039/a706268k
Abstract
The regioselectivity of the Baeyer–Villiger oxidation of norbornan-7-ones can be steered by the distal 2-endo-substituents present. Hydrolysis of the resulting bicyclic lactones provides a stereospecific route to functionalized cyclohexanes.Keywords
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