In Support of the Original Medermycin/Lactoquinomycin A Structure
- 27 November 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 4 (26) , 4659-4662
- https://doi.org/10.1021/ol027086g
Abstract
Herein we report a significant body of spectroscopic data that supports the originally proposed structure of medermycin/lactoquinomycin A. In addition, we demonstrate that these data are inconsistent with the revised structure reported recently in the literature.Keywords
This publication has 6 references indexed in Scilit:
- Use of Long-Range C-H Heteronuclear Multiple Bond Connectivity in the Assignment of the 13 C NMR Spectra of Complex Organic MoleculesCurrent Organic Chemistry, 2001
- J‐IMPEACH‐MBC: a new concatenated NMR experiment for F1 scalable, J‐resolved HMBCMagnetic Resonance in Chemistry, 2001
- One‐ and two‐dimensional gradient‐selected HSQMBC NMR experiments for the efficient analysis of long‐range heteronuclear coupling constantsMagnetic Resonance in Chemistry, 2000
- Macromodel—an integrated software system for modeling organic and bioorganic molecules using molecular mechanicsJournal of Computational Chemistry, 1990
- 13C,1H spin–spin coupling. X—Norbornane: A reinvestigation of the karplus curve for3J(13C,1H)Magnetic Resonance in Chemistry, 1990
- Metabolic products of microorganisms. 240 Urdamycins, new angucycline antibiotics from Streptomyces fradiae. II Structural studies of urdamycins B to F.The Journal of Antibiotics, 1987