4-Connected Metal−Organic Assemblies Mediated via Heterochelation and Bridging of Single Metal Ions: Kagomé Lattice and the M6L12 Octahedron
- 27 April 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (20) , 7266-7267
- https://doi.org/10.1021/ja051259q
Abstract
Single-metal-ion-based rigid molecular building blocks (MBBs) have been utilized to design and synthesize novel metal-organic assemblies. Reaction between In(NO3)3.2H2O and 2,5-pyridinedicarboxylic acid (2,5-H2PDC) has permitted the assembly of two supramolecular isomers, a Kagomé lattice and an unprecedented M6L12 discrete octahedron.Keywords
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