Conversion of aliphatic and alicyclic carboxylic acids into nor-hydroperoxides, nor-alcohols, and nor-oxo derivatives using radical chemistry
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 242-244
- https://doi.org/10.1039/c39840000242
Abstract
Radicals generated from esters of N-hydroxypyridine-2-thione react smoothly with oxygen in the presence of t-butyl thiol to furnish nor-hydroperoxides, from which the corresponding alcohols and carbonyl derivatives can be readily obtained.Keywords
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