The solvent effect on the α-effect
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 595
- https://doi.org/10.1039/c39860000595
Abstract
The reaction of p-nitrophenyl acetate with butane-2,3-dione monoximate anion as the α-nucleophile, compared with p-chlorophenoxide ion as the normal nucleophile, exhibits a maximum in rate enhancement (‘α-effect’) in dimethyl sulphoxide–water mixtures as the medium composition is varied.Keywords
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