Diastereoselective aldol reactions of β-silylenolates
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 305-306
- https://doi.org/10.1039/c39860000305
Abstract
β-Silylenolates react with aldehydes with high diastereoselectivity with respect to both new chiral centres, the relative stereochemistry in the aldol relationship being dependent upon the geometry of the enolate double bond.Keywords
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