Synthesis, Characterization and Theoretical Evaluation of [Ti(NC4Me4)(NMe2)3] - A Complex with N-Bonded 2,3,4,5-Tetramethylpyrrolyl Ligand
- 1 January 1998
- journal article
- Published by Institute of Organic Chemistry & Biochemistry in Collection of Czechoslovak Chemical Communications
- Vol. 63 (2) , 182-186
- https://doi.org/10.1135/cccc19980182
Abstract
The complex [Ti(NC4Me4)(NMe2)3] has been synthesized, characterized by mass spectrometry, 1H and 13C NMR and theoretically studied by ab initio molecular orbital calculations. The N-σ-coordination mode of the heterocyclic ring was predicted by the 13C NMR data and confirmed by the optimized geometry of the model complex [Ti(NC4H4)(NMe2)3]. The different bonding modes of the 2,3,4,5-tetramethylpyrrolyl ligand are discussed.Keywords
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