Observation of pentacarbonylchromium on flash photolysis of hexacarbonylchromium in cyclohexane solution
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 105-106
- https://doi.org/10.1039/c39730000105
Abstract
The first observable transient (lifetime > 50 ns) on flash photolysis of Cr(CO)6 is Cr(CO)5, which is the precursor of two species previously assigned to the D3h and C4v forms of Cr(CO)5, and now shown to arise from reaction with impurities.Keywords
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