The Structure of Cryolite-Alumina Melts
- 1 January 1960
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 107 (12) , 997-1001
- https://doi.org/10.1149/1.2427589
Abstract
The integrated cryoscopic equation, Temkin's formulation for ionic melts, and recent findings on the constitution of molten cryolite are employed to evaluate several reaction mechanisms for the solution of alumina in cryolite. The reaction mechanism that emerges as the most probable from a plot of . The deviation from linearity of the plot for this reaction at high alumina contents can be attributed to some dimerization of the ions to give ions.Keywords
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