Enantioselective Pauson-Khand Reactions Mediated by a Chiral Amine N-Oxide
- 1 October 1995
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1995 (10) , 1085-1086
- https://doi.org/10.1055/s-1995-5170
Abstract
The first example of an asymmetric version of the Pauson-Khand cyclisation promoted solely by a chiral amine N-oxide, brucine N-oxide, is reported. This amine N-oxide has been utilised in the Pauson-Khand annulation to give excellent yields and good enantiomeric excesses of cyclopentenone at low temperature.Keywords
This publication has 0 references indexed in Scilit: