An Improved Conversion of Cyclohexanones into 1-Methyl-2-Formylcyclohexenes
- 1 January 1974
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 4 (5) , 297-301
- https://doi.org/10.1080/00397917408064084
Abstract
The 1,2-disubstituted cyclohexene synthon shown in structure is found in several natural products (e.g. cyclolavandulal, )1 as well as in numerous useful synthetic intermediates (e.g. →→ tachysterols)2. Our interest in novel applications of electrocyclic reactions to natural products synthesis required a general synthesis for a variety of structures of type .Keywords
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