Highly selective trimerisation of MeNC by a novel titanium imido complex containing a tridentate dianionic ligand
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 16,p. 1555-1556
- https://doi.org/10.1039/a703275g
Abstract
A new type of imido compound [Ti(NBu t )L(py)] 1 containing a tripodal dianionic ligand is reported which effects the remarkably selective trimerisation of MeNC; the crystal structures of 1 and [TiL{N(Me)N(Bu t )(C 4 H 3 N 2 M e)}] 2 are described [L = MeC(2-C 5 H 4 N)(CH 2 NSiMe 3 ) 2 ].Keywords
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