Retention of configuration at the titanium atom upon oxo–peroxo ligand substitution of titanium(IV) porphyrins
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 570-571
- https://doi.org/10.1039/c39790000570
Abstract
N.m.r. spectra of oxo- and peroxo-titanium(IV) complexes of a suitably substituted tetraphenylporphyrin suggest that formation of the peroxo-species from the oxo-compound and hydrogen peroxide takes place with retention of configuration; labelling experiments indicate that this ligand exchange is a true substitution, i.e. the O–O bond of H2O2 remains intact in the peroxo complex.Keywords
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