The first successful direct metallation of ethene
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 260-261
- https://doi.org/10.1039/c39860000260
Abstract
Vinyl potassium was formed directly from ethene by use of a new butyl-lithium–potassium t-butoxide–tetramethylethylenediamine metallating reagent; typical products were obtained with 1-bromo-octane and, after addition of LiBr in tetrahydrofuran, with benzaldehyde and diphenyl disulphide.Keywords
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