Stereospecific Conjugate Alkenyl Group Transfer to α,β-Enones Using Vinylalane Reagents
- 1 July 1973
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 51 (13) , 2098-2101
- https://doi.org/10.1139/v73-314
Abstract
Trans- Alkenyl alanes (easily prepared by hydroalumination of an acetylene) promote the stereospecific 1,4- delivery of the olefinic unit to conjugated ketones. This new conjugate addition reaction provides easy access to trans-γ,δ-unsaturated ketones which would otherwise be available with difficulty.Keywords
This publication has 0 references indexed in Scilit: