Activation of benzene carbon–hydrogen bonds by palladium(II) acetate–dialkyl sulphide systems
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 941-942
- https://doi.org/10.1039/c39870000941
Abstract
Benzene is directly activated by palladium(II) acetate-dialkyl sulphide systems at 70 °C to afford acetato-bridged diphenyltripalladium(II) complexes [(R2S)PhPd(µ-MeCO2)2Pd(µ-MeCO2)2PdPh(SR2)], which are regarded as intermediate species in the catalytic arylation of alkenes and carbonylation of arenes by palladium(II) acetate.Keywords
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