Mono N-functionalization of cyclic and linear tetraamines via their tridentate tricarbonylchromium complexes
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 206-207
- https://doi.org/10.1039/c39910000206
Abstract
The fac-LCr(CO)3 tridentate complexes of 1,4,7,10-tetraazacyclododecane 1, 1,4,8,11-tetraazacyclotetradecane 2, 1,4,7,10-tetraazadecane 3 and 1,5,8,12-tetraazadodecane 4 have been selectively alkylated in high yield at the uncomplexed nitrogen atom, giving rise to mono N-functionalized tetraamines and bis-macrocyclic compounds.Keywords
This publication has 9 references indexed in Scilit:
- Developments in functionalization of macrocyclic polyaminesPure and Applied Chemistry, 1989
- Characterisation of tridentate macrocyclic complexes of molybdenum(0) with tetra-aza macrocycles. Crystal structure of [ Mo(CO)3L1](L1= C-meso-5,5,7,12,12,14-hexamethyl-1,4,8,11 -tetra-azacyclotetradecane)J. Chem. Soc., Dalton Trans., 1989
- PolyaminesAnnual Review of Plant Physiology, 1985
- The physiology and biochemistry of polyamines in plantsArchives of Biochemistry and Biophysics, 1984
- Reactions of LM(CO)3 complexes (M = Cr, Mo, W; L = 1,4,7-triazacyclononane) with bromine, iodine, and nitric acid. Syntheses of air-stable hydridocarbonyl and hydridonitrosyl complexes. Crystal structure of [LMo(CO)3Br](ClO4).H2OInorganic Chemistry, 1984
- Synthesis and metal complexes of aza-macrocycles with pendant arms having additional ligating groupsPublished by Springer Nature ,1984
- Role of polyamines in macromolecular synthesisTrends in Biochemical Sciences, 1981
- Effects of Polyamines on the Structure and Reactivity of tRNAProgress in Nucleic Acid Research and Molecular Biology, 1976
- Vibrational Spectra and Bonding in Metal Carbonyls. III. Force Constants and Assignments of CO Stretching Modes in Various Molecules; Evaluation of CO Bond OrdersInorganic Chemistry, 1964