Co-ordinatively unsaturated molybdenum and tungsten cyclopentadienyl complexes; molecular structures of [WCl(CF₃C₂CF₃)₂(η⁵-C₅H₅)] and [Mo(C₄F₆)₂(C₅H₅)₂]

1 January 1974

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 17,p. 706b-708
https://doi.org/10.1039/c3974000706b

Abstract

Reaction of [MCl(CO)₃(η⁵-C₅H₅)](M = Mo or W) with acetylenes affords the 16-electron species [MCl-(RC₂R)₂(η⁵-C₅H₅)]; structurally characterised by X-ray crystallography, and shown to react with donor ligands and with TlC₅H₅.

Keywords

MOLECULAR STRUCTURE

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Co-ordinatively unsaturated molybdenum and tungsten cyclopentadienyl complexes; molecular structures of [WCl(CF3C2CF3)2(η5-C5H5)] and [Mo(C4F6)2(C5H5)2]

Abstract

Keywords

Co-ordinatively unsaturated molybdenum and tungsten cyclopentadienyl complexes; molecular structures of [WCl(CF₃C₂CF₃)₂(η⁵-C₅H₅)] and [Mo(C₄F₆)₂(C₅H₅)₂]