Five-co-ordinate high-spin complexes of divalent nickel and copper with 2-methayl-8-[(6-methyl-2-pyridyl)methyleneamino]quinoline
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2907-2909
- https://doi.org/10.1039/j19700002907
Abstract
The tridentate ligand 2-methyl-8-[(6-methyl-2-pyridyl)methyleneamino]quinoline (mpq) forms high-spin five-co-ordinate complexes with nickel(II) and copper(II) of the type [M(mpq)X2], xH2O (X = Cl, Br, I, NO3, or ClO4), for which a trigonal bipyramidal structure is proposed. Analytical, spectral, and conductivity data support this assignment.Keywords
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